Advances in Organic Synthesis

Volume: 6

Indexed in: EBSCO, Ulrich's Periodicals Directory

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities ...
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Recent Advances in P,N-Containing Ligands for Transition-Metal Homogeneous Catalysis

Pp. 3-58 (56)

Ioannis D. Kostas

Abstract

Phosphorus- and nitrogen-containing ligands are among the most important and widely used heterodentate ligands for transition-metal homogeneous catalysis (asymmetric or otherwise). The present review combines information on recent advances in the syntheses of these ligands, their coordination chemistry with transitionmetals and their applications to homogeneous catalysis.

Keywords:

Transition-metal homogeneous catalysis, asymmetric catalysis, hydrogenation, hydroformylation, hydrosilylation, allylic alkylation, amination, heck reaction, suzuki reaction, negishi reaction, oligomerization, P, N-ligands, hybrid ligands, hemilabile ligands, chiral ligands, pincer ligands, phosphine, phosphite, phosphinite, phosphoramidite.

Affiliation:

National Hellenic Research Foundation, Institute of Biology, Medicinal Chemistry and Biotechnology, Vas. Constantinou 48, 116 35 Athens, Greece