Advances in Organic Synthesis

Volume: 4

Indexed in: Scopus, Chemical Abstracts, EBSCO, Ulrich's Periodicals Directory

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities ...
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Reactions of Nitrogen Derivatives of Carbonyl Compounds with Phenyliodoso Diacetate in Organic Synthesis

Pp. 267-316 (50)

Antigoni Kotali, Elvira Kotali, Ioannis S. Lafazanis and Philip A. Harris

Abstract

The progress that has been made in organic synthesis via the reactions of nitrogen derivatives of carbonyl compounds with phenyliodoso diacetate is presented. The synthesis of various aliphatic, alicyclic and heterocyclic compounds is discussed. Emphasis is given in a synthetically useful new transformation of hydroxyl into a carbonyl group that leads to high yield synthesis of 1,2-diacyl-substituted compounds.

Keywords:

Phenyliodoso diacetate, diacetoxy iodobenzene, hydrazones, Nacylhydrazones, oximes, semicarbazones, oxidation, transformation, hypervalent iodine, lead tetraacetate, phenyliodoso bis(trifluoroacetate), C-C bond formation, o-diacetylbenzene, 1, 2, 3, 4-tetraacylbenzene, 3, 4-diacylcoumarins, 7, 8- diacylcoumarins, fulleroisoxazolines, oxadiazoles, triazoles, deprotection.

Affiliation:

Laboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki, GR-54124, Greece