Advances in Organic Synthesis

Volume: 4

Indexed in: Chemical Abstracts, EBSCO, Ulrich's Periodicals Directory

Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challenging structures. It presents comprehensive articles written by eminent authorities ...
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Rhodium-Catalyzed Hydroformylation Promoted by Modified Cyclodextrins: Current Scope and Future Developments

Pp. 36-63 (28)

Frédéric Hapiot, Loïc Leclercq, Nathalie Azaroual, Sophie Fourmentin, Sébastien Tilloy and Eric Monflier

Abstract

The contribution of modified cyclodextrins in aqueous biphasic rhodiumcatalyzed hydroformylation of higher olefins is tackled, taking into account previous results and new experimental data. The role of the cyclodextrins is emphasized and discussed through the analysis of numerous parameters. Development outlooks are also presented.

Keywords:

Hydroformylation, olefin, aldehyde, rhodium, water soluble phosphine, water soluble ligand, amphiphilic ligand, biphasic catalysis, phase transfer catalysis, interfacial catalysis, thermoregulated catalysis, catalyst recycling, mass transfer, micelle, cyclodextrin, host guest chemistry, inclusion complex, supramolecular adduct, High Pressure NMR spectroscopy, 1H Diffusion-Ordered NMR spectroscopy, surface tension, molecular dynamics.

Affiliation:

Université d’Artois, Unité de Catalyse et de Chimie du Solide, UMR CNRS 8181, Rue Jean Souvraz SP 18, 62307 Lens Cédex, France