Synthesis of 2,5-Substituted Tetrahydrofurans by Pd(II)-Catalyzed Cyclization

Author(s): Beata Olszewska, Boguslaw Kryczka, Anna Zawisza.

Journal Name: Letters in Organic Chemistry

Volume 9 , Issue 8 , 2012

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Abstract:

The Pd(II)-catalyzed cyclization of hydroxyl-substituted allylic alcohols quantitatively afforded a cis/trans mixture of 2,5-substituted tetrahydrofurans.

Keywords: Cyclization, diastereoselectivity, homogeneous catalysis, oxygen heterocycles, palladium, Transition-metal-catalyzed, carbonyl, π-olefin, palladium, substrate.

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Article Details

VOLUME: 9
ISSUE: 8
Year: 2012
Page: [563 - 567]
Pages: 5
DOI: 10.2174/157017812802850258
Price: $65

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