Diphenyl-2-Pyridylphosphine Based Palladium Catalysts for the Suzuki- Miyaura Reactions in Environment Friendly Solvents

Author(s): Archana Tairai, Nasifa Shahnaz, Chandan Sarmah, Pankaj Das.

Journal Name: Letters in Organic Chemistry

Volume 9 , Issue 7 , 2012

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Abstract:

Three palladium complexes derived from diphenyl-2-pyridylphosphine (PPh2Py) were investigated for their utility as catalysts for the Suzuki-Miyaura reactions of aryl halides in environment friendly solvents such as water, alcohols etc. Good-to-excellent yields of coupling products were achieved with a wide range of aryl halides under mild reaction conditions.

Keywords: Aqueous condition, diphenyl-2-pyridylphosphine, hemilabile ligand, palladium catalyst, room temperature, suzuki-miyaura reaction, biphenyl-type phosphine, phosphapalladacycles, bidentate phosphine, arylboronic, P-monodentate

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Article Details

VOLUME: 9
ISSUE: 7
Year: 2012
Page: [509 - 515]
Pages: 7
DOI: 10.2174/157017812802139690
Price: $65

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